发明公开
EP0448206A2 Substituted benzimidazole and indazole derivatives, processes for their preparation and their use as herbicides 失效
取代的苯并咪唑和吲唑衍生物,它们的制备方法和它们作为除草剂的用途。

Substituted benzimidazole and indazole derivatives, processes for their preparation and their use as herbicides
摘要:
A herbicidal compound of formula (I) :
or N-oxide or quaternised derivative thereof;

in which the dotted lines indicate the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;
Ar is an optionally substituted aryl or heterocyclic ring system;
W is 0 or NR 1
where R 1 is H or lower alkyl;
A, B, D are independently selected from N, NR 2 , N-E, CR 6 , C-E or C(R 6 )E;
wherein E is:
provided 2 of A, B and D are N, NR 2 or N-E and at least one of A, B or D carries a group E;
where R 2 is H, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 3 and R 4 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR 9 R 10 , or
R 3 and R 4 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;
R 5 is CO 2 R 11 , CN, COR 11 , CH 2 OR 11 , CH(OH)R", CH(OR 11 )R 12 , CSNH 2 , COSR 11 , CSOR", CONHSO 2 R 11 , CONR 13 R 14 , CONHNR 13 R 14 , CONHN + R 13 R 14 R 15 Y-, CO 2 -M + or COON=CR 13 R 14 ;
X is (CH 2 ) n , CH=CH, CH(OR 16 )CH 2 or COCH z ;
where n is 0, 1 or 2;
M is an agriculturally acceptable cation;
Y- is an agriculturally acceptable anion;
R 6 is H, halogen, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 7 and R 8 are independently H or lower alkyl;
R 11 , R 12 and R 16 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group; and
R 9 , R 10 , R 13 , R 14 and R 15 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group or any two of R 9 , R 10 , R 13 , R 14 and R 15 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring providing that the compound is other than 5-(2,4-dichlorophenoxy)indazol-1- ylacetic acid or its methyl ester.

Process for the preparation of these compounds and compositions containing them are also described.
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