发明公开
EP0448206A2 Substituted benzimidazole and indazole derivatives, processes for their preparation and their use as herbicides
失效
取代的苯并咪唑和吲唑衍生物,它们的制备方法和它们作为除草剂的用途。
- 专利标题: Substituted benzimidazole and indazole derivatives, processes for their preparation and their use as herbicides
- 专利标题(中): 取代的苯并咪唑和吲唑衍生物,它们的制备方法和它们作为除草剂的用途。
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申请号: EP91300954.4申请日: 1991-02-06
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公开(公告)号: EP0448206A2公开(公告)日: 1991-09-25
- 发明人: Barton, John Edward Duncan , Cartwright, David , McCormack, Derek
- 申请人: ZENECA LIMITED
- 申请人地址: 15 Stanhope Gate London W1Y 6LN GB
- 专利权人: ZENECA LIMITED
- 当前专利权人: ZENECA LIMITED
- 当前专利权人地址: 15 Stanhope Gate London W1Y 6LN GB
- 代理机构: Waterman, John Richard
- 优先权: GB9003548 19900216; GB9003549 19900216; GB9016979 19900802; GB9023984 19901105; GB9026810 19901210
- 主分类号: C07D231/56
- IPC分类号: C07D231/56 ; C07D235/06 ; C07D235/10 ; C07D235/24 ; C07D401/12 ; C07D235/08 ; C07D235/26 ; C07D235/22 ; C07C217/90 ; C07C205/38 ; C07C255/25
摘要:
A herbicidal compound of formula (I) :
or N-oxide or quaternised derivative thereof;
in which the dotted lines indicate the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;
Ar is an optionally substituted aryl or heterocyclic ring system;
W is 0 or NR 1
where R 1 is H or lower alkyl;
A, B, D are independently selected from N, NR 2 , N-E, CR 6 , C-E or C(R 6 )E;
wherein E is:
provided 2 of A, B and D are N, NR 2 or N-E and at least one of A, B or D carries a group E;
where R 2 is H, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 3 and R 4 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR 9 R 10 , or
R 3 and R 4 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;
R 5 is CO 2 R 11 , CN, COR 11 , CH 2 OR 11 , CH(OH)R", CH(OR 11 )R 12 , CSNH 2 , COSR 11 , CSOR", CONHSO 2 R 11 , CONR 13 R 14 , CONHNR 13 R 14 , CONHN + R 13 R 14 R 15 Y-, CO 2 -M + or COON=CR 13 R 14 ;
X is (CH 2 ) n , CH=CH, CH(OR 16 )CH 2 or COCH z ;
where n is 0, 1 or 2;
M is an agriculturally acceptable cation;
Y- is an agriculturally acceptable anion;
R 6 is H, halogen, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 7 and R 8 are independently H or lower alkyl;
R 11 , R 12 and R 16 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group; and
R 9 , R 10 , R 13 , R 14 and R 15 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group or any two of R 9 , R 10 , R 13 , R 14 and R 15 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring providing that the compound is other than 5-(2,4-dichlorophenoxy)indazol-1- ylacetic acid or its methyl ester.
Process for the preparation of these compounds and compositions containing them are also described.
or N-oxide or quaternised derivative thereof;
in which the dotted lines indicate the presence of two double bonds arranged so as to form a fused hetero-aromatic ring system;
Ar is an optionally substituted aryl or heterocyclic ring system;
W is 0 or NR 1
where R 1 is H or lower alkyl;
A, B, D are independently selected from N, NR 2 , N-E, CR 6 , C-E or C(R 6 )E;
wherein E is:
provided 2 of A, B and D are N, NR 2 or N-E and at least one of A, B or D carries a group E;
where R 2 is H, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 3 and R 4 are independently selected from H, optionally substituted alkyl, alkenyl or alkynyl, halogen, NR 9 R 10 , or
R 3 and R 4 together with the carbon to which they are attached form an optionally substituted alkenyl or cycloalkyl group;
R 5 is CO 2 R 11 , CN, COR 11 , CH 2 OR 11 , CH(OH)R", CH(OR 11 )R 12 , CSNH 2 , COSR 11 , CSOR", CONHSO 2 R 11 , CONR 13 R 14 , CONHNR 13 R 14 , CONHN + R 13 R 14 R 15 Y-, CO 2 -M + or COON=CR 13 R 14 ;
X is (CH 2 ) n , CH=CH, CH(OR 16 )CH 2 or COCH z ;
where n is 0, 1 or 2;
M is an agriculturally acceptable cation;
Y- is an agriculturally acceptable anion;
R 6 is H, halogen, OR 7 , CN, COOR 8 , alkyl or haloalkyl;
R 7 and R 8 are independently H or lower alkyl;
R 11 , R 12 and R 16 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group; and
R 9 , R 10 , R 13 , R 14 and R 15 are independently selected from H or an optionally substituted alkyl, alkenyl, alkynyl or aryl group or any two of R 9 , R 10 , R 13 , R 14 and R 15 together with the atom to which they are attached form a cycloalkyl or heterocyclic ring providing that the compound is other than 5-(2,4-dichlorophenoxy)indazol-1- ylacetic acid or its methyl ester.
Process for the preparation of these compounds and compositions containing them are also described.
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