发明公开
- 专利标题: Process for the gas-phase polymerization of olefins
- 专利标题(中): 油相的气相聚合方法
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申请号: EP92109376.1申请日: 1992-06-03
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公开(公告)号: EP0517183A3公开(公告)日: 1993-01-20
- 发明人: Covezzi, Massimo , Galli, Paolo , Govoni, Gabriele , Rinaldi, Roberto
- 申请人: Himont Incorporated , SPHERILENE S.r.l.
- 申请人地址: Three Little Falls Centre 2801 Centerville Road P.O. Box 15439 Wilmington Delaware 19850-5439 US
- 专利权人: Himont Incorporated,SPHERILENE S.r.l.
- 当前专利权人: Himont Incorporated,SPHERILENE S.r.l.
- 当前专利权人地址: Three Little Falls Centre 2801 Centerville Road P.O. Box 15439 Wilmington Delaware 19850-5439 US
- 代理机构: Zumstein, Fritz, Dr.
- 优先权: ITRM910379 19910603
- 主分类号: C08F10/00
- IPC分类号: C08F10/00 ; C08F2/34 ; C08F297/08
摘要:
Process for the gas-phase polymerization of olefins of the formula CH₂=CHR in which R is hydrogen or an alkyl or aryl radical with 1 to 8 carbon atoms carried out in one or more reactors having a fluidized or mechanically agitated bed, using a catalyst obtained by reaction of a titanium halide or haloalcoholate and optionally an electron-donor compound supported on an active Mg dihalide with an Al-trialkyl compound and optionally an electron-donor compound, comprising the steps of: a) contacting the catalyst components in the absence of the olefin; b) prepolymerizing propylene or mixtures of propylene with minor amounts of ethylene or an alpha-olefin to form a propylene polymer with an insolubility in xylene of at least 60% by weight, in an amount of from 0.5 to 1000 g per g solid catalyst component; and c) polymerizing one or more CH₂=CHR olefins in the gas phase in the presence of the prepolymer-catalyst system obtained in b) while maintaining in the gas phase an alkane in a molar concentration with respect to the olefin of from 20 to 80%.
公开/授权文献
- EP0517183A2 Process for the gas-phase polymerization of olefins 公开/授权日:1992-12-09
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