发明公开
EP0729447A4 METHOD OF MAKING 1,1-BIS-(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
失效
用于生产1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷
- 专利标题: METHOD OF MAKING 1,1-BIS-(4-HYDROXYPHENYL)-3,3,5-TRIMETHYLCYCLOHEXANE
- 专利标题(中): 用于生产1,1-双(4-羟基苯基)-3,3,5-三甲基环己烷
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申请号: EP95932375申请日: 1995-09-05
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公开(公告)号: EP0729447A4公开(公告)日: 1998-06-10
- 发明人: RUBINO MARK R , SALEK JEFFREY S
- 申请人: ARISTECH CHEMICAL CORPORARION
- 专利权人: ARISTECH CHEMICAL CORPORARION
- 当前专利权人: ARISTECH CHEMICAL CORPORARION
- 优先权: US30712794 1994-09-16
- 主分类号: C07D317/72
- IPC分类号: C07D317/72 ; B01J27/10 ; B01J31/02 ; C07C37/11 ; C07C37/14 ; C07C39/17 ; C07C319/14 ; C07C323/61 ; C07D319/08 ; C07D327/04 ; C07D327/06 ; C07C37/00
摘要:
This invention provides a unique method of producing 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane ('BPTMC'). The disclosed method manufactures BPTMC from ketals and hemithioketals of 3,3,5-trimethylcyclohexanone ('TMC'). The reaction takes place in the presence of an acid catalyst, and optionally added co-catalysts. Additionally, applicants have disclosed a particularly useful method of manufacturing BPTMC from TMC and alcohol and/or thiol starting materials. These starting materials react to form the TMC ketal or thioketal materials. This method is particularly useful in that it allows recovery and recycling of the alcohol and/or thiol.
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