- 专利标题: Process for the synthesis of fluorinated alkyl sulphonyl halides
- 专利标题(中): 烯丙基烷基磺酰卤
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申请号: EP96104685.1申请日: 1996-03-25
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公开(公告)号: EP0736524A2公开(公告)日: 1996-10-09
- 发明人: Zavilla, John , Hommeltoft, Sven Ivar
- 申请人: Haldor Topsoe A/S
- 申请人地址: Nymollevej 55 DK-2800 Lyngby DK
- 专利权人: Haldor Topsoe A/S
- 当前专利权人: Haldor Topsoe A/S
- 当前专利权人地址: Nymollevej 55 DK-2800 Lyngby DK
- 优先权: DK383/95 19950405
- 主分类号: C07C309/80
- IPC分类号: C07C309/80 ; C07C303/10
摘要:
For the preparation of fluorinated alkyl sulphonyl halides having the general formula:
where R I f is fluorinated alkyl group and R II f is a fluorinated alkyl group or fluorine, X is a halogen atom, and Y is a proton, a halogen atom, or a fluorinated alkyl groups,
by reaction of a corresponding fluorinated unsaturated hydrocarbon with sulphuryl halide, wherein the reaction is carried out in the presence of at least catalytic amounts of a fluoride in a solvent comprising compounds having one or more SO and/or SO 2 groups incorporated in the compound structure.
where R I f is fluorinated alkyl group and R II f is a fluorinated alkyl group or fluorine, X is a halogen atom, and Y is a proton, a halogen atom, or a fluorinated alkyl groups,
by reaction of a corresponding fluorinated unsaturated hydrocarbon with sulphuryl halide, wherein the reaction is carried out in the presence of at least catalytic amounts of a fluoride in a solvent comprising compounds having one or more SO and/or SO 2 groups incorporated in the compound structure.
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