发明授权
EP0797703B1 PEROXIDE BLEACHING PROCESS FOR CELLULOSIC AND LIGNOCELLULOSIC MATERIAL
无效
方法过氧化物漂白纤维素和木质纤维材料
- 专利标题: PEROXIDE BLEACHING PROCESS FOR CELLULOSIC AND LIGNOCELLULOSIC MATERIAL
- 专利标题(中): 方法过氧化物漂白纤维素和木质纤维材料
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申请号: EP95926123.1申请日: 1995-06-29
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公开(公告)号: EP0797703B1公开(公告)日: 2000-02-09
- 发明人: SHACKFORD, Lewis, D. , MILLER, William, J. , ROY, Brian, P. , VAN LIEROP, Barbara , BERRY, Richard, M.
- 申请人: BELOIT TECHNOLOGIES, INC. , Pulp and Paper Research Institute of Canada
- 申请人地址: 3513 Concord Pike, Suite 3001 Wilmington, Delaware 19803 US
- 专利权人: BELOIT TECHNOLOGIES, INC.,Pulp and Paper Research Institute of Canada
- 当前专利权人: BELOIT TECHNOLOGIES, INC.,Pulp and Paper Research Institute of Canada
- 当前专利权人地址: 3513 Concord Pike, Suite 3001 Wilmington, Delaware 19803 US
- 代理机构: Schmitz, Jean-Marie
- 优先权: US273539 19940711
- 国际公布: WO9601920 19960125
- 主分类号: D21C9/16
- IPC分类号: D21C9/16 ; D21C9/10 ; D06L3/02
摘要:
A method for bleaching cellulosic and lignocellulosic pulp using hydrogen peroxide as a bleaching reagent, utilizes a two-step reaction, viz. a short high temperature step at a pressure sufficient to suppress boiling and a longer atmospheric pressure reduced temperature step to consume a substantial portion of the hydrogen peroxide remaining after the short phase. The method includes the steps of introducing pulp (15), at a consistency of 10 %-18 %, to a mixer (100) in which the pulp is heated to a temperature above 100 DEG C; adding sufficient sodium hydroxide to bring the pulp to a pH of 8.5; adding sufficient hydrogen peroxide (36) to equal from about 0.5 %-5.0 %, by weight, of the pulp; passing the pulp through a pressurized reactor column (400) at a rate providing a reaction time in the column of between 1 and 30 minutes; and depositing the pulp in a reaction tower and allowing the reaction to proceed for 1-5 hours until a substantial portion of the residual hydrogen peroxide has been consumed. It may be desirable to introduce the pulp to a mixer and add alkali to reactivate residual hydrogen peroxide by bringing the pulp to a pH of at least 9 between bleaching steps.
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