发明公开
- 专利标题: A polyolefin catalyst for polymerization of propylene and a method of making and using thereof
- 专利标题(中): 用于丙烯聚合的聚烯烃催化剂及其制备方法和用途
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申请号: EP97122171.8申请日: 1997-12-16
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公开(公告)号: EP0849287A1公开(公告)日: 1998-06-24
- 发明人: Shamshoum, Edwar S. , Bauch, Christopher G. , Rauscher, David J.
- 申请人: FINA TECHNOLOGY, INC.
- 申请人地址: 8350 North Central Expressway Dallas, Texas 75206 US
- 专利权人: FINA TECHNOLOGY, INC.
- 当前专利权人: FINA TECHNOLOGY, INC.
- 当前专利权人地址: 8350 North Central Expressway Dallas, Texas 75206 US
- 代理机构: Leyder, Francis
- 优先权: US770882 19961220
- 主分类号: C08F4/654
- IPC分类号: C08F4/654 ; C08F10/00 ; C08F4/646
摘要:
A method of forming a polyolefin catalyst component which includes chlorinating magnesium ethoxide, and then treating the solid first with an electron donor, particularly diethyl phthalate or di-isobutyl phthalate, at a relatively low donor level, and then second with a titanating agent, such as titanium tetrachloride, to produce a catalyst component. The catalyst component is activated with an aluminum alkyl cocatalyst. An organosilane compound can be added as a stereoselectivity control agent. The activated catalyst is used in the polymerization of olefins, particularly propylene, to obtain a polymer product with a broad molecular weight distribution.
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