发明公开
EP0860452A1 Improved electron donor and catalyst system for monomer polymerization
失效
Verbesserte Electronen-Donor und Katalysatorsystemfürdie Polymerisation von Monomeren
- 专利标题： Improved electron donor and catalyst system for monomer polymerization
- 专利标题（中）： Verbesserte Electronen-Donor und Katalysatorsystemfürdie Polymerisation von Monomeren
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申请号： EP98103104.0申请日： 1998-02-23
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公开(公告)号： EP0860452A1公开(公告)日： 1998-08-26
- 发明人: Shamshoum, Edwar S. , Bauch, Christopher G. , Harris, Theodore G. , Kim, Sehyun , Rauscher, David J.
- 申请人： FINA TECHNOLOGY, INC.
- 申请人地址： 8350 North Central Expressway Dallas, Texas 75206 US
- 专利权人： FINA TECHNOLOGY, INC.
- 当前专利权人： FINA TECHNOLOGY, INC.
- 当前专利权人地址： 8350 North Central Expressway Dallas, Texas 75206 US
- 代理机构： Leyder, Francis
- 优先权： US804498 19970221
- 主分类号： C08F10/00
- IPC分类号： C08F10/00 ; C08F4/646
摘要：
Provided is process of polymerizing monomer having at least one Ziegler-Natta polymerizable bond, comprising contacting monomer with, reacting monomer in presence of, or combinations thereof, catalyst system comprising:
A) catalyst component consisting essentially of
i) about 1.5 weight % to about 6 weight % titanium,
ii) about 10 weight % to about 20 weight % magnesium,
iii) about 40 weight % to about 70 weight % halogen,
iv) about 5 weight % to about 25 weight % polycarboxylic ester selected from the group consisting of esters aliphatic, aromatic, alicyclic polycarboxylic acids, or combinations thereof or alkyl phthalates, and
v) about 0.1 weight percent to about 2.5 weight % organic phosphorous compound selected from the group consisting of hydrocarbon esters of phosphoric acid such that each hydrocarbon group has one to about six carbon atoms;
B) electron donor described by the formula:
wherein R 1 is alkyl or cycloakylgroup containing at least one secondary or tertiary carbon atom, R 2 and R 3 are each independently alkyl or aryl group, and R 4 is an alkyl group having a primary carbon bonded to the silicon atom; and
C) organic aluminum compound.
A) catalyst component consisting essentially of
i) about 1.5 weight % to about 6 weight % titanium,
ii) about 10 weight % to about 20 weight % magnesium,
iii) about 40 weight % to about 70 weight % halogen,
iv) about 5 weight % to about 25 weight % polycarboxylic ester selected from the group consisting of esters aliphatic, aromatic, alicyclic polycarboxylic acids, or combinations thereof or alkyl phthalates, and
v) about 0.1 weight percent to about 2.5 weight % organic phosphorous compound selected from the group consisting of hydrocarbon esters of phosphoric acid such that each hydrocarbon group has one to about six carbon atoms;
B) electron donor described by the formula:
wherein R 1 is alkyl or cycloakylgroup containing at least one secondary or tertiary carbon atom, R 2 and R 3 are each independently alkyl or aryl group, and R 4 is an alkyl group having a primary carbon bonded to the silicon atom; and
C) organic aluminum compound.
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