发明授权
- 专利标题: VERFAHREN ZUR ANIONISCHEN POLYMERISATION
- 专利标题(英): Anionic polymerisation process
- 专利标题(中): 方法阴离子聚合
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申请号: EP97941943.9申请日: 1997-08-18
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公开(公告)号: EP0918805B2公开(公告)日: 2007-08-22
- 发明人: FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , LÄTSCH, Stefan , LOTH, Wolfgang , SCHADE, Christian , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
- 申请人: BASF Aktiengesellschaft
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: 67056 Ludwigshafen DE
- 优先权: DE19633272 19960819; DE19633273 19960819; DE19715036 19970411; DE19731419 19970722
- 国际公布: WO1998007765 19980226
- 主分类号: C08F12/08
- IPC分类号: C08F12/08 ; C08F36/00 ; C08F4/44
摘要:
A continuous anionic polymerisation or copolymerisation process of styrene or diene monomers with alkali metal alkyl as polymerisation initiator is carried out in the presence of a metal alkyl or aryl of an at least bivalent element as reaction speed regulator, preferably in non-isotherm conditions and without a back admixture in a pipe or pipe bundle reactor. A metal alkyl or aryl A of formula R1M1 and a metal alkyl or aryl B of formula R2nM2 in a molar ratio between B and A from 0.1:1 to 500:1 are used. In the formulas, M1 is Li, Na or K; R1 is hydrogen, C¿1?-C20-alkyl or C6-C20-aryl or C7-C20-alkyl-substituted aryl; M?2¿ is an n-valent element of groups 2a, 2b or 3a of the periodic table of elements; and R2 is hydrogen, halogen, C¿1?-C20-alkyl or C6-C20-alkyl. Also disclosed is a special initiator for the anionic polymerisation which does not contain any Lewis bases.
公开/授权文献
- EP0918805B1 VERFAHREN ZUR ANIONISCHEN POLYMERISATION 公开/授权日:2002-06-12
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