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公开(公告)号：EP0918805B2
公开(公告)日：2007-08-22
申请号：EP97941943.9
申请日：1997-08-18
发明人： FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , LÄTSCH, Stefan , LOTH, Wolfgang , SCHADE, Christian , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F279/02 , C08F4/46 , C08F4/54 , C08F4/52 , C08F4/48 , C08F212/08
摘要： A continuous anionic polymerisation or copolymerisation process of styrene or diene monomers with alkali metal alkyl as polymerisation initiator is carried out in the presence of a metal alkyl or aryl of an at least bivalent element as reaction speed regulator, preferably in non-isotherm conditions and without a back admixture in a pipe or pipe bundle reactor. A metal alkyl or aryl A of formula R1M1 and a metal alkyl or aryl B of formula R2nM2 in a molar ratio between B and A from 0.1:1 to 500:1 are used. In the formulas, M1 is Li, Na or K; R1 is hydrogen, C¿1?-C20-alkyl or C6-C20-aryl or C7-C20-alkyl-substituted aryl; M?2¿ is an n-valent element of groups 2a, 2b or 3a of the periodic table of elements; and R2 is hydrogen, halogen, C¿1?-C20-alkyl or C6-C20-alkyl. Also disclosed is a special initiator for the anionic polymerisation which does not contain any Lewis bases.
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公开(公告)号：EP0918805B1
公开(公告)日：2002-06-12
申请号：EP97941943.9
申请日：1997-08-18
发明人： FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , LÄTSCH, Stefan , LOTH, Wolfgang , SCHADE, Christian , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F279/02 , C08F4/46 , C08F4/54 , C08F4/52 , C08F4/48 , C08F212/08
摘要： A continuous anionic polymerisation or copolymerisation process of styrene or diene monomers with alkali metal alkyl as polymerisation initiator is carried out in the presence of a metal alkyl or aryl of an at least bivalent element as reaction speed regulator, preferably in non-isotherm conditions and without a back admixture in a pipe or pipe bundle reactor. A metal alkyl or aryl A of formula R1M1 and a metal alkyl or aryl B of formula R2nM2 in a molar ratio between B and A from 0.1:1 to 500:1 are used. In the formulas, M1 is Li, Na or K; R1 is hydrogen, C¿1?-C20-alkyl or C6-C20-aryl or C7-C20-alkyl-substituted aryl; M?2¿ is an n-valent element of groups 2a, 2b or 3a of the periodic table of elements; and R2 is hydrogen, halogen, C¿1?-C20-alkyl or C6-C20-alkyl. Also disclosed is a special initiator for the anionic polymerisation which does not contain any Lewis bases.
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公开(公告)号：EP1017731A1
公开(公告)日：2000-07-12
申请号：EP98947441.6
申请日：1998-08-19
CPC分类号： C08F12/08 , C08L25/04 , C08L25/06 , C08L2205/02 , C08L2666/04
摘要： The invention relates to styrene polymers with a bimodal molecular weight distribution having a high molecular weight fraction determined from the representation of the molar mass distribution, of at least 5 surface percent, and a molecular weight at a maximum peak Mp of at least 800,000 g/mol. These styrene polymers can be obtained through anionic polymerisation from vinylaromatic monomers with at least one double initiator dose.
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公开(公告)号：EP1017731B1
公开(公告)日：2002-11-13
申请号：EP98947441.6
申请日：1998-08-19
CPC分类号： C08F12/08 , C08L25/04 , C08L25/06 , C08L2205/02 , C08L2666/04
摘要： The invention relates to styrene polymers with a bimodal molecular weight distribution having a high molecular weight fraction determined from the representation of the molar mass distribution, of at least 5 surface percent, and a molecular weight at a maximum peak Mp of at least 800,000 g/mol. These styrene polymers can be obtained through anionic polymerisation from vinylaromatic monomers with at least one double initiator dose.
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5.发明授权VERFAHREN ZUR HERSTELLUNG VON DIENPOLYMERISATLÖSUNGEN IN VINYLAROMATISCHEN MONOMEREN 失效用于生产DIENPOLYMERISATLÖSUNGEN乙烯基芳族单体
公开(公告)号：EP0918806B1
公开(公告)日：2000-11-08
申请号：EP97944765.3
申请日：1997-08-18
发明人： LÄTSCH, Stefan , FISCHER, Wolfgang , GAUSEPOHL, Hermann , WARZELHAN, Volker , SCHADE, Christian
IPC分类号： C08F212/04 , C08F236/10 , C08F279/02 , C08F297/04
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6.发明公开VERFAHREN ZUR HERSTELLUNG VON DIENPOLYMERISATLÖSUNGEN IN VINYLAROMATISCHEN MONOMEREN 失效用于生产DIENPOLYMERISATLÖSUNGEN乙烯基芳族单体
公开(公告)号：EP0918806A1
公开(公告)日：1999-06-02
申请号：EP97944765.0
申请日：1997-08-18
发明人： LÄTSCH, Stefan , FISCHER, Wolfgang , GAUSEPOHL, Hermann , WARZELHAN, Volker , SCHADE, Christian
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F4/46 , C08F4/52 , C08F4/54 , C08F4/48
摘要： A process is disclosed for anionically polymerising dienes or for copolymerising dienes and vinyl aromatic monomers in a vinyl aromatic monomer or monomer mixture into homopolydienes or copolymers or mixed homopolydienes and copolymers in the presence of a metal alkyl or aryl of an at least bivalent element, without the admixture of Lewis bases.
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公开(公告)号：EP0918805A2
公开(公告)日：1999-06-02
申请号：EP97941943.0
申请日：1997-08-18
发明人： FISCHER, Wolfgang , GAUSEPOHL, Hermann , KNOLL, Konrad , LÄTSCH, Stefan , LOTH, Wolfgang , SCHADE, Christian , WARZELHAN, Volker , FONTANILLE, Michel , DEFFIEUX, Alain , DESBOIS, Philippe
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F279/02 , C08F4/46 , C08F4/54 , C08F4/52 , C08F4/48 , C08F212/08
摘要： A continuous anionic polymerisation or copolymerisation process of styrene or diene monomers with alkali metal alkyl as polymerisation initiator is carried out in the presence of a metal alkyl or aryl of an at least bivalent element as reaction speed regulator, preferably in non-isotherm conditions and without a back admixture in a pipe or pipe bundle reactor. A metal alkyl or aryl A of formula R1M1 and a metal alkyl or aryl B of formula R2nM2 in a molar ratio between B and A from 0.1:1 to 500:1 are used. In the formulas, M1 is Li, Na or K; R1 is hydrogen, C¿1?-C20-alkyl or C6-C20-aryl or C7-C20-alkyl-substituted aryl; M?2¿ is an n-valent element of groups 2a, 2b or 3a of the periodic table of elements; and R2 is hydrogen, halogen, C¿1?-C20-alkyl or C6-C20-alkyl. Also disclosed is a special initiator for the anionic polymerisation which does not contain any Lewis bases.
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