发明公开
- 专利标题: IMPROVED PROCESSING OLEFIN COPOLYMERS
- 专利标题(中): 与改进的加工烯烃聚合物
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申请号: EP98906326.0申请日: 1998-02-06
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公开(公告)号: EP0958323A1公开(公告)日: 1999-11-24
- 发明人: GARCIA-FRANCO, Cesar , LOHSE, David, John , MENDELSON, Robert, Allen , MILNER, S., T. , FETTERS, Lewis, John
- 申请人: EXXON CHEMICAL PATENTS INC.
- 申请人地址: 5200 Bayway Drive Baytown, TX 77520-5200 US
- 专利权人: EXXON CHEMICAL PATENTS INC.
- 当前专利权人: EXXON CHEMICAL PATENTS INC.
- 当前专利权人地址: 5200 Bayway Drive Baytown, TX 77520-5200 US
- 代理机构: Dew, Melvyn John, et al
- 优先权: US19970037323P 19970207; US19970037149P 19970214; US19970065739P 19971117
- 国际公布: WO1998034986 19980813
- 主分类号: C08F2
- IPC分类号: C08F2 ; C08F8 ; C08F255 ; C08F257 ; C08F279 ; C08F290 ; C08F297 ; C08G81 ; C08L23 ; C08L51 ; C08L55 ; C08L101 ; C08F110 ; C08F210
摘要:
The invention is directed to essentially saturated hydrocarbon polymer composition comprising essentially saturated hydrocarbon polymers having A) a backbone chain; B) a plurality of essentially hydrocarbyl sidechains connected to A), said sidechains each having a number-average molecular weight of from 2500 Daltons to 125,000 Daltons and an MWD by SEC of 1.0-3.5; and having A) a Newtonian limiting viscosity (θ0) at 190 °C at least 50 % greater than that of a linear olefinic polymer of the same chemical composition and weight average molecular weight, preferably at least twice as great as that of said linear polymer; B) a ratio of the rubbery plateau modulus at 190 °C to that of a linear polymer of the same chemical composition less than 0.5, preferably ∫0.3; C) a ratio of the Newtonian limiting viscosity (θ0) to the absolute value of the complex viscosity in oscillatory shear (θ*) at 100 rad/sec at 190 °C of at least 5; and D) a ratio of the extensional viscosity measured at a strain rate of 1 sec-1, 190 °C, and time = 3 sec (i.e., a strain of 3) to that predicted by linear viscoelasticity at the same temperature and time of 2 or greater. Ethylene-butene prepared by anionic polymerization and hydrogenation illustrate and ethylene-hexene copolymers prepared by coordination polymerization illustrate the invention. The invention polymers exhibit improved processing characteristics in that the shear thinning behavior closely approaches that of ideal polymers and exhibit improved strain thickening.
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