发明公开
EP0990631A4 PROCESS FOR COOXIDIZING ORGANIC COMPOUNDS, PROCESS FOR PRODUCING EPOXY COMPOUNDS AND PROCESS FOR PRODUCING ESTERS OR LACTONES 有权
有机化合物,PROCESS FOR PRODUCING环氧衍生物及其制造方法酯或内酯的方法共氧化

PROCESS FOR COOXIDIZING ORGANIC COMPOUNDS, PROCESS FOR PRODUCING EPOXY COMPOUNDS AND PROCESS FOR PRODUCING ESTERS OR LACTONES
摘要:
A process for cooxidizing organic compounds which comprises, in the presence of an imide compound such as N-hydroxyphthalimide, oxidizing with molecular oxygen a compound (A) which is selected from among (A1) compounds having nonaromatic ethylenic linkage and (A2) ketones or alcohols corresponding to the ketones and a compound (B) which can be oxidized by the above imide compound with oxygen and is different from the above compound (A). As the compound (B), use can be made of (a) primary or secondary alcohols (benzhydrol, cyclohexanol, etc.), and (b) compounds having a carbon-hydrogen bond adjacent to an unsaturated bond (tetralin, ethylbenzene, etc.). Use of this process makes it possible to obtain the corresponding epoxy compounds from (A1) compounds having nonaromatic ethylenic linkage, and the corresponding esters or lactones from (A2) ketones or alcohols corresponding to the ketones, each at a high yield.
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