发明公开
EP0990631A4 PROCESS FOR COOXIDIZING ORGANIC COMPOUNDS, PROCESS FOR PRODUCING EPOXY COMPOUNDS AND PROCESS FOR PRODUCING ESTERS OR LACTONES
有权
有机化合物,PROCESS FOR PRODUCING环氧衍生物及其制造方法酯或内酯的方法共氧化
- 专利标题: PROCESS FOR COOXIDIZING ORGANIC COMPOUNDS, PROCESS FOR PRODUCING EPOXY COMPOUNDS AND PROCESS FOR PRODUCING ESTERS OR LACTONES
- 专利标题(中): 有机化合物,PROCESS FOR PRODUCING环氧衍生物及其制造方法酯或内酯的方法共氧化
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申请号: EP99909321申请日: 1999-03-23
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公开(公告)号: EP0990631A4公开(公告)日: 2004-09-01
- 发明人: ISHII YASUTAKA , NAKANO TATSUYA
- 申请人: DAICEL CHEM , ISHII YASUTAKA
- 专利权人: DAICEL CHEM,ISHII YASUTAKA
- 当前专利权人: DAICEL CHEM,ISHII YASUTAKA
- 优先权: JP10045998 1998-03-27; JP12421598 1998-04-16; JP2032599 1999-01-28
- 主分类号: B01J31/02
- IPC分类号: B01J31/02 ; B01J31/20 ; B01J31/22 ; C07B41/12 ; C07D315/00 ; C07B41/00 ; C07B33/00 ; C07D301/06 ; C07D303/04 ; C07D303/14 ; C07D303/16
摘要:
A process for cooxidizing organic compounds which comprises, in the presence of an imide compound such as N-hydroxyphthalimide, oxidizing with molecular oxygen a compound (A) which is selected from among (A1) compounds having nonaromatic ethylenic linkage and (A2) ketones or alcohols corresponding to the ketones and a compound (B) which can be oxidized by the above imide compound with oxygen and is different from the above compound (A). As the compound (B), use can be made of (a) primary or secondary alcohols (benzhydrol, cyclohexanol, etc.), and (b) compounds having a carbon-hydrogen bond adjacent to an unsaturated bond (tetralin, ethylbenzene, etc.). Use of this process makes it possible to obtain the corresponding epoxy compounds from (A1) compounds having nonaromatic ethylenic linkage, and the corresponding esters or lactones from (A2) ketones or alcohols corresponding to the ketones, each at a high yield.
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