发明公开
- 专利标题: PROCESS FOR PRODUCING FLUOROPOLYMER
- 专利标题(中): 用于生产聚合物FLUOR
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申请号: EP99926925申请日: 1999-07-05
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公开(公告)号: EP1153946A4公开(公告)日: 2006-09-27
- 发明人: KITAICHI MASANORI , AIHARA HIROSHI , IRIE SADASHIGE , KISHINE MITSURU , UETA YUTAKA , OTANI KATSUHIDE , MARUYA YOSHIKI , SAITO HIDEYA , TSUKAMOTO MITSUO
- 申请人: DAIKIN IND LTD
- 专利权人: DAIKIN IND LTD
- 当前专利权人: DAIKIN IND LTD
- 优先权: JP19133798 1998-07-07
- 主分类号: C08F14/18
- IPC分类号: C08F14/18 ; C08F2/10 ; C08F14/26 ; C08F14/28 ; C08F214/18 ; C08F259/08 ; C08F295/00
摘要:
A process for fluoropolymer production which is effective in improving the productivity of the emulsion polymerization method while maintaining the excellent material properties of the fluoropolymer, which comprises: (a) a first polymerization step in which a fluoromonomer or a monomer mixture of a fluoromonomer and a nonfluorinated monomer is emulsion-polymerized in the presence of a radical polymerization initiator and an emulsifying agent in an aqueous medium; (b) a dilution step in which the resultant aqueous emulsion of polymer particles is diluted with water to reduce both the number of emulsified polymer particles per unit amount of the aqueous medium and the concentration of the emulsifying agent; and (c) a second polymerization step in which the fluoromonomer and/or nonfluorinated monomer is emulsion-polymerized in the diluted emulsion.
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