发明公开
- 专利标题: METHOD OF STABILIZING FLUOROPOLYMER
- 专利标题(中): 方法用于稳定含氟聚合物
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申请号: EP99951179申请日: 1999-11-01
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公开(公告)号: EP1170303A4公开(公告)日: 2004-03-31
- 发明人: HIRAGA YOSHIYUKI , KOMATSU SATOSHI , NODA TOMOHISA , UTSUMI YASUHIRO
- 申请人: DAIKIN IND LTD
- 专利权人: DAIKIN IND LTD
- 当前专利权人: DAIKIN IND LTD
- 优先权: JP31366998 1998-11-04; JP25052699 1999-09-03
- 主分类号: C08F6/00
- IPC分类号: C08F6/00 ; C08F8/00 ; C08F14/00 ; C08J3/00
摘要:
A method by which unstable groups of a melt-processable fluoropolymer can be stabilized rapidly and efficiently. The resultant stabilized polymer through melt molding gives a molded article free from not only air inclusions or voids but also discoloration. The method is characterized by melt-kneading a melt-processable fluoropolymer having unstable groups in a kneader having a stabilization zone satisfying the following requirements: (1) an oxygen-containing gas is present in the stabilization zone and (2) water is present in that zone. Preferably, (3) the absolute pressure in the zone is regulated to 0.2 MPa or higher; or (a) an oxygen-containing gas is present in the zone in an amount sufficient to enable the stabilized fluoropolymer to have a carbon radical spin number of 5x1013 spins/g or smaller as determined by electron spin resonance (ESR) spectroscopy at a temperature of 77 K and (b) water is present in that zone.
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