发明公开
EP1173452A1 METALLORGANISCHE KATALYSATOREN FÜR DIE POLYMERISATION UNGESÄTTIGTER VERBINDUNGEN
有权
METALLORGANISCHE KATALYSATORENFÜRDIE POLYMERISATIONUNGESÄTTIGTERVERBINDUNGEN
- 专利标题: METALLORGANISCHE KATALYSATOREN FÜR DIE POLYMERISATION UNGESÄTTIGTER VERBINDUNGEN
- 专利标题(英): Metal organic catalysts for polymerizing unsaturated compounds
- 专利标题(中): METALLORGANISCHE KATALYSATORENFÜRDIE POLYMERISATIONUNGESÄTTIGTERVERBINDUNGEN
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申请号: EP00927137.0申请日: 2000-05-04
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公开(公告)号: EP1173452A1公开(公告)日: 2002-01-23
- 发明人: GONIOUKH, Andrei , MICKLITZ, Wolfgang , BILDSTEIN, Benno , MALAUN, Michael , HRADSKY, Andreas
- 申请人: BASF AKTIENGESELLSCHAFT
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: 67056 Ludwigshafen DE
- 优先权: DE19920486 19990504
- 国际公布: WO0066600 20001109
- 主分类号: C07F17/00
- IPC分类号: C07F17/00 ; C07F17/02 ; C07C249/02 ; C08F10/00
摘要:
The invention relates to a method for producing 1,2-diimine compounds of general formula (I) in which the symbols have the following meanings: R?1 and R2¿, independent of one another, represent alkyl radicals, aryl radicals or metallocenyl radicals; and R3, R4, independent of one another, represent H, alkyl radicals or aryl radicals; or R3, R4 form a cyclic radical together so that, including both imine carbon atoms, a 5- to 8-member ring is formed which can be saturated and unsaturated or arbitrarily substituted with hydrocarbon radicals. The inventive compounds are produced by reacting 1,2-dicarbonyl compounds with primary amines, whereby the amines are activated with trialkylaluminum compounds before being reacted with the 1,2-dicarbonyl compounds. The invention also relates to 1,2-diimine compounds of general formula (I), wherein R?1 and R2¿, independent of one another, are metallocenyl radicals. Finally, the invention relates to metal complexes comprised of compounds of formula (I) and to the use of these metal complexes as catalysts in a method for polymerizing unsaturated compounds.
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