- 专利标题: VERFAHREN ZUR HERSTELLUNG VON ALKYL-SUBSTITUIERTEN BUTENOLEN
- 专利标题(英): Method for producing alkyl-substituted butenols
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申请号: EP00964140.8申请日: 2000-09-08
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公开(公告)号: EP1212272A1公开(公告)日: 2002-06-12
- 发明人: HECK, Stephan , FRIESENHAGEN, Lothar , KLEIN, Norbert , MARKERT, Thomas , PELZER, Gerrit , SCHNEIDER, Markus
- 申请人: Cognis Deutschland GmbH & Co. KG
- 申请人地址: Postfach 13 01 64 40551 Düsseldorf DE
- 专利权人: Cognis Deutschland GmbH & Co. KG
- 当前专利权人: Cognis Deutschland GmbH & Co. KG
- 当前专利权人地址: Postfach 13 01 64 40551 Düsseldorf DE
- 优先权: DE19944524 19990917
- 国际公布: WO0121568 20010329
- 主分类号: C07C45/74
- IPC分类号: C07C45/74 ; C07C47/225 ; C07C29/141 ; C07C33/12
摘要:
The invention relates to a method for producing alkyl-substituted butenols of the general formula (I): R1-CH2-CH=CR2-CH2OH, wherein R1 represents a saturated or olefinically unsaturated alkyl or cycloalkyl group with 4 to 16 carbon atoms that can be optionally substituted by an alkyl, cycloalkyl, aryl or alkaryl group with the proviso that said substituent has a maximum of 12 carbon atoms and R2 represents hydrogen or an alkyl group with 1 to 6 carbon atoms. The inventive butenols can be obtained in high yields and high purity by reacting the aldehydes of formula (II) R1-CH2-CHO, wherein R1 has the same meaning as in formula (I), with the corresponding lower aldehydes and then reducing the unsaturated aldehydes obtained if (i) the aldol condensation is carried out in an inert organic solvent and (ii) the unsaturated aldehydes are reduced in the presence of optionally calcined copper-zinc. The reduction in step (ii) is carried out in a continuous and isothermal process and at temperatures ranging from 45 - 60 °C and at a hydrogen pressure in the range of from 1 to 300 bar.
公开/授权文献
- EP1212272B1 VERFAHREN ZUR HERSTELLUNG VON ALKYL-SUBSTITUIERTEN BUTENOLEN 公开/授权日:2003-12-10
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