发明授权
- 专利标题: PROCESS FOR THE SYNTHESIS OF MIXTURES OF METHANE DIPHENYL DIAMINE AND ITS HIGHER HOMOLOGUES WITH A CONTROLLED ISOMER DISTRIBUTION
- 专利标题(中): 用于生产二氨基二苯甲烷和混合物及其高级同系物以受控的异构体
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申请号: EP02745272.1申请日: 2002-04-29
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公开(公告)号: EP1381589B1公开(公告)日: 2006-07-26
- 发明人: DE ANGELIS, Alberto , PEREGO, Carlo , FARIAS, Otello , BOSETTI, Aldo
- 申请人: DOW GLOBAL TECHNOLOGIES INC.
- 申请人地址: Washington Street, 1790 Building Midland, Michigan 48674 US
- 专利权人: DOW GLOBAL TECHNOLOGIES INC.
- 当前专利权人: DOW GLOBAL TECHNOLOGIES INC.
- 当前专利权人地址: Washington Street, 1790 Building Midland, Michigan 48674 US
- 代理机构: Raynor, John
- 优先权: ITMI20010880 20010427
- 国际公布: WO2002088067 20021107
- 主分类号: C07C209/54
- IPC分类号: C07C209/54 ; C07C209/78
摘要:
A process for preparing methane diphenyl diamine (MDA) or a mixture of methane diphenyl diamine (MDA) and its higher homologues with a controlled isomer distribution using a modified zeolite having 'shape selectivity'. The mixture contains compounds having the following general formula (I): where R represents a hydrogen atom or a C1 to C8 (iso)alkyl group, a C4 to C10 cycloalkyl group or a C6 to C12 aromatic group and n is a whole number greater than or equal to one so as to give a functionality of 2 to 6.
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