VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG VON 3,3'-DICHLOR-BENZIDIN-DIHIDROCHLORID
    3.
    发明授权
    VERFAHREN ZUR KONTINUIERLICHEN HERSTELLUNG VON 3,3'-DICHLOR-BENZIDIN-DIHIDROCHLORID 失效
    工艺为3,3'-二氯联苯胺DIHIDROCHLORID连续生产。

    公开(公告)号:EP0499611B1

    公开(公告)日:1994-07-27

    申请号:EP90915996.4

    申请日:1990-11-03

    IPC分类号: C07C209/54

    CPC分类号: C07C209/54

    摘要: Process for the continuous production of 3,3'-dichloro-benzidine dihydrochloride from 2-2'-dichloro-hydrazobenzole by treatment with aqueous sulphuric acid by continuously adding to the 2-2'-dichlorohydrazobenzole dissolved in an aromatic solvent which is not miscible with water, at about 20 to 50 °C in the presence of an alkaline metal salt of an alkyl(C8-C23) polyglycol ether sulphate, such a quantity of 50 to 80 % aqueous sulphuric acid that the suspension formed remains transportable and then also continuously diluting the suspension emerging from the reaction region with water and heating it to about 90 to 95 °C until a solution is obtained, separating the aromatic solvent from the hot sulphuric acid aqueous phase, causing the 3-3'-dichloro-benzidine dihydrochloride to precipitate by the addition of hydrochloric acid to the remaining sulphuric acid solution and filtering it.