发明公开
- 专利标题: PROCESS FOR PRODUCTION OF FLUOROPOLYMER
- 专利标题(中): 用于生产含氟聚合物
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申请号: EP03791360申请日: 2003-08-28
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公开(公告)号: EP1541591A4公开(公告)日: 2008-10-15
- 发明人: TSUKAMOTO MITSUO , OTOI KENJI , HIRAGA YOSHIYUKI , NAKAYA HIDEKI , ICHISAKA TOSHIKI
- 申请人: DAIKIN IND LTD
- 专利权人: DAIKIN IND LTD
- 当前专利权人: DAIKIN IND LTD
- 优先权: JP2002248560 2002-08-28
- 主分类号: C08F2/00
- IPC分类号: C08F2/00 ; B01J3/00 ; C08F14/18
摘要:
The invention provides a process for the production of a fluoropolymer having a high molecular weight and a narrow molecular weight distribution. A process for the production of a fluoropolymer by continuous polymerization of a radical-polymerizable monomer in a specific reaction field, characterized in that the specific reaction field is in a supercritical state having a pressure of 40Mpa or below and a temperature lower than the lowest temperature at which the specific reaction field exhibits a supercritical state plus 100°C, that the radical -polymerizable monomer is a fluoroolefin monomer, and that the fluoropolymer has a weight-average molecular weight [Mw]in terms of polystyrene of 150,000 or above and an [Mw]/[Mn] ratio exceeding 1 and up to 3 (wherein [Mw] is as defined above and [Mn] is a number-average molecular weight in terms of polystyrene).
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