发明授权
- 专利标题: HEAT-SENSITIVE POSITIVE WORKING LITHOGRAPHIC PRINTING PLATE PRECURSOR WITH A HIGH RESISTANCE TO CHEMICALS
- 专利标题(中): 热敏感正型平版具有高耐化学性印版原版
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申请号: EP03790933.0申请日: 2003-08-28
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公开(公告)号: EP1543046B1公开(公告)日: 2006-05-10
- 发明人: TIMPE, Hans-Joachim , MÜLLER, Ursula , SAVARIAR-HAUCK, Celin
- 申请人: Kodak Polychrome Graphics GmbH
- 申请人地址: An der Bahn 80 37520 Osterode/Harz DE
- 专利权人: Kodak Polychrome Graphics GmbH
- 当前专利权人: Kodak Polychrome Graphics GmbH
- 当前专利权人地址: An der Bahn 80 37520 Osterode/Harz DE
- 代理机构: Vossius & Partner
- 优先权: DE10239505 20020828
- 国际公布: WO2004020484 20040311
- 主分类号: C08F8/14
- IPC分类号: C08F8/14 ; C08L29/14 ; C08F8/28 ; C08K5/06 ; B41C1/10 ; B41M5/36 ; B41M5/40
摘要:
Heat-sensitive element comprising (a) an optionally pre-treated substrate (b) a positive working heat-sensitive coating comprising (i) at least one novolak resin, (ii) at least one component which reduces the aqueous alkaline developer solubility of novolak, wherein said reduction in solubility is reversed upon the application of heat, and (iii) at least one acidic polyvinyl acetal comprising the structural units (A), (B), (C) (A) (B) (C) and (D) wherein (D) is at least one unit selected from (D-1), (D-2), and (D-3): (D-1) (D-2) (D-3) wherein R1 is a hydrogen atom or a C1-C4 alkyl group, R2 is a hydrogen atom or a C1-C18 alkyl group, R3 is a hydrogen atom or a C1-C4 alkyl group, R4 is a hydrogen atom or a C1-C4 alkyl group, R5 is -COOH, -(CH2)a-COOH, -O-(CH2)a-COOH, -SO3H, -PO3H2 or -PO4H2, a is an integer from 1 to 8, and X is selected from -(CR6R7)n- and -CR8=CR9- wherein n is an integer of 1 to 6, each R6 and R7 is independently selected from a hydrogen atom and C1-C6 alkyl group, and R8 and R9 are independently selected from a hydrogen atom and a C1- C6 alkyl group or R8 and R9 together with the two carbon atoms to which they are bonded, form an optionally substituted aryl or heteroaryl group, wherein components (i) and (ii) do not have to be present as separate substances but may be used in the form of an appropriately functionalized novolak.
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