- 专利标题: VERFAHREN ZUR HERSTELLUNG GERUCHSARMER HYDROGEL-BILDENDER POLYMERISATE
- 专利标题(英): Method for the production of low-odor hydrogel-forming polymers
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申请号: EP03785770.3申请日: 2003-12-08
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公开(公告)号: EP1583779A1公开(公告)日: 2005-10-12
- 发明人: NESTLER, Gerhard , MÜLLER-ENGEL, Klaus Joachim , WICKEL, Stefan
- 申请人: BASF Aktiengesellschaft
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: 67056 Ludwigshafen DE
- 代理机构: Reitstötter - Kinzebach
- 优先权: DE10257449 20021209
- 国际公布: WO2004052949 20040624
- 主分类号: C08F20/06
- IPC分类号: C08F20/06 ; A61L15/60 ; C07C51/43
摘要:
The invention relates to a method for producing low-odor, hydrogel-forming polymers based on acrylic acid. Said method comprises the following steps: a) a polymeric hydrogel is produced by radically polymerizing a monomer composition containing at least 50 percent by weight of acrylic acid in an aqueous polymerizing medium, and the hydrogel is transformed into a particle-shaped hydrogel or a powder forming a hydrogel; and optionally b) the particle-shaped hydrogel or the powder forming a hydrogel is treated with a crosslinking substance comprising at least two functional groups that are reactive towards the carboxyl groups of the polymer, optionally in a latent form. The inventive method is characterized by the fact that the acrylic acid used in step a) comprises a total amount of oligomers of less than 500 ppm, preferably no more than 400 ppm, and especially no more than 300 ppm, ppm referring to proportions by weight relative to the acrylic acid. Advantageously, the proportion of triacrylic acid (compound I in which x = 2) and higher oligomers of the acrylic acid amounts to less than 100 ppm, especially less than 50 ppm, and particularly less than 10 ppm.
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