发明公开
- 专利标题: POLYMER, PROCESS AND COMPOSITION
- 专利标题(中): 聚合物,方法和组合物
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申请号: EP10798802.4申请日: 2010-12-21
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公开(公告)号: EP2516513A1公开(公告)日: 2012-10-31
- 发明人: FRIEDERICHS, Joseph Petronella , VERMEULEN, Jacobus Adriaan Antonius , DRIESSEN, Marco Marcus Matheus
- 申请人: DSM IP Assets B.V.
- 申请人地址: Het Overloon 1 6411 TE Heerlen NL
- 专利权人: DSM IP Assets B.V.
- 当前专利权人: DSM IP Assets B.V.
- 当前专利权人地址: Het Overloon 1 6411 TE Heerlen NL
- 代理机构: Kirk, Martin John
- 优先权: EP09180162 20091221
- 国际公布: WO2011076785 20110630
- 主分类号: C08G81/00
- IPC分类号: C08G81/00 ; C08G83/00 ; C08K5/00
摘要:
There is described a process for producing a gel free hyperbranched polyamide polymer having primary amino groups (useful as a crosslinker). The process comprises the step of reacting at least one diamine and at least one unsaturated diester in a molar ratio of diamine to diester greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation. The diamine in kept in excess with at least 5% of water by total weight of the diamine and diester, a reaction temperature less than the boiling point of the diamine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (-C=C- ) double bonds; and >95% ester [-C(O)=O] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion.
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