发明授权
- 专利标题: PRODUCTION OF MYRTANAL FROM BETA-PINENE EPOXIDE
- 专利标题(中): 从β-蒎烯环氧化物生产MYRTANAL
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申请号: EP10842924.2申请日: 2010-12-17
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公开(公告)号: EP2518042B1公开(公告)日: 2018-03-28
- 发明人: CORMA CANÓS, Avelino , RENZ, Michael , DE LA TORRE ALFARO, Olalla
- 申请人: Consejo Superior De Investigaciones Científicas (CSIC) , Universidad Politécnica De Valencia (UPV)
- 申请人地址: Serrano 117 28006 Madrid ES
- 专利权人: Consejo Superior De Investigaciones Científicas (CSIC),Universidad Politécnica De Valencia (UPV)
- 当前专利权人: Consejo Superior De Investigaciones Científicas (CSIC),Universidad Politécnica De Valencia (UPV)
- 当前专利权人地址: Serrano 117 28006 Madrid ES
- 代理机构: Pons
- 优先权: ES200931260 20091223
- 国际公布: WO2011086208 20110721
- 主分类号: C07C47/34
- IPC分类号: C07C47/34 ; C07C45/58 ; B01J29/89 ; B01J29/06 ; C01B39/02
摘要:
The present invention relates to a procedure for the production of myrtanal from ²-pinene epoxide, comprising as a minimum putting said epoxide in contact with a crystalline microporous catalyst having pores of diameter of at least 0.52 nm and having an empirical formula in dehydrated calcined form of H w (M w Ti x Sn y Zr z Si 1-w-x-and-z )O 2 , where M is at least one metal of valency +3 selected from among Al, B, Ga, Fe, Cr, and combinations thereof; w is a molar fraction of M having a value between 0 and 2(x+y+z); x is a molar fraction of titanium having a value between 0 and 0.06; y is a molar fraction of tin having a value between 0 and 0.06; z is a molar fraction of zirconium having a value between 0 and 0.064, and wherein at least one of the three values "x", "y" or "z" differs from zero. In the present invention it is preferable for the crystalline microporous catalyst to have pores of at least 0.52 nm and a crystalline structure having an x-ray diffractogram corresponding to a beta zeolite.
公开/授权文献
- EP2518042A1 PRODUCTION OF MYRTANAL FROM BETA-PINENE EPOXIDE 公开/授权日:2012-10-31
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