发明公开
EP3192078A1 PROCEDE DE PREPARATION D'UN MATERIAU SOLIDE NANOCOMPOSITE A BASE D'HEXA- ET OCTACYANOMETALLATES DE METAUX ALCALINS
审中-公开
PROCEDE DE PREPARATION D'UN MATERIAU SOLIDE NANOCOMPOSITE A BASE D'HEXA-ET OCTACYANOMETALLATES DE METAUX ALCALINS
- 专利标题： PROCEDE DE PREPARATION D'UN MATERIAU SOLIDE NANOCOMPOSITE A BASE D'HEXA- ET OCTACYANOMETALLATES DE METAUX ALCALINS
- 专利标题（英）： Method for producing a solid nanocomposite material based on hexa- and octacyanometallates of alkali metals
- 专利标题（中）： PROCEDE DE PREPARATION D'UN MATERIAU SOLIDE NANOCOMPOSITE A BASE D'HEXA-ET OCTACYANOMETALLATES DE METAUX ALCALINS
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申请号： EP15763312.4申请日： 2015-09-11
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公开(公告)号： EP3192078A1公开(公告)日： 2017-07-19
- 发明人: GRANDJEAN, Agnès , BARRE, Yves
- 申请人： Commissariat à l'Énergie Atomique et aux Énergies Alternatives
- 申请人地址： 25, Rue Leblanc Bâtiment "Le Ponant D" 75015 Paris FR
- 专利权人： Commissariat à l'Énergie Atomique et aux Énergies Alternatives
- 当前专利权人： Commissariat à l'Énergie Atomique et aux Énergies Alternatives
- 当前专利权人地址： 25, Rue Leblanc Bâtiment "Le Ponant D" 75015 Paris FR
- 代理机构： Brevalex
- 优先权： FR1458594 20140912
- 国际公布： WO2016038206 20160317
- 主分类号： G21F9/12
- IPC分类号： G21F9/12 ; B01J39/16 ; B01J20/02 ; B01J20/06 ; B01J20/30 ; B01D71/02 ; G21F9/30
摘要：
The invention relates to a method for producing a solid nanocomposite material comprising nanoparticles of a metal coordination polymer with ligands CN, said nanoparticles satisfying the formula [Alk
+
x ]M
n+ [M'(CN)
m ]
z- where Alk is an alkali metal, x is 1 or 2, M is a transition metal, n is 2 or 3, M' is a transition metal, m is 6 or 8, and z is 3 or 4; said cations M
n+ of the coordination polymer being bound by an organometallic bond or a coordination bond to an organic group R2 of an organic graft, and said organic graft furthermore being chemically bound, preferably by a covalent bond, to at least one surface of a solid support, by a reaction of a group RI of said graft with said surface.
+
x ]M
n+ [M'(CN)
m ]
z- where Alk is an alkali metal, x is 1 or 2, M is a transition metal, n is 2 or 3, M' is a transition metal, m is 6 or 8, and z is 3 or 4; said cations M
n+ of the coordination polymer being bound by an organometallic bond or a coordination bond to an organic group R2 of an organic graft, and said organic graft furthermore being chemically bound, preferably by a covalent bond, to at least one surface of a solid support, by a reaction of a group RI of said graft with said surface.
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