An environmentally sequestered nuclear spent fuel pool in one embodiment includes sidewalls and a base slab that confine a water impoundment. The pool includes fuel racks containing spent fuel assemblies which heat the water via radioactive decay. A dual liner system enclosing the pool forms an impervious barrier providing redundant provisions for preventing leakage of contaminated pool water into the environment. An interstitial space is formed between the liners which may be maintained at sub-atmospheric pressures by a vacuum pump system that evacuates the space. By maintaining the pressure in the space at a negative pressure with corresponding boiling point less than the temperature of the pool water, any leakage through the inner-most liner into the interstitial space will vaporize and be extracted via the pump for signaling a potential leak in the liner system.