- 专利标题: METHOD FOR PRODUCING WET-PROCESS PHOSPHORIC ACID AND BY-PRODUCING ALPHA-HEMIHYDRATE GYPSUM AND HIGH-PURITY AND HIGH-WHITENESS ALPHA-HEMIHYDRATE GYPSUM
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申请号: EP16845633.3申请日: 2016-08-26
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公开(公告)号: EP3351507A1公开(公告)日: 2018-07-25
- 发明人: HU, Zhaoping , YAO, Hualong , CHEN, Hongkun , PANG, Shihua , LIU, Yongxiu , LI, Chengzhi
- 申请人: Kingenta Norsterra Chemical Co., Ltd.
- 申请人地址: Industrial Park Weng' an County QianNan Buyi and Miao Autonomous Prefecture Guizhou 550400 CN
- 专利权人: Kingenta Norsterra Chemical Co., Ltd.
- 当前专利权人: Kingenta Norsterra Chemical Co., Ltd.
- 当前专利权人地址: Industrial Park Weng' an County QianNan Buyi and Miao Autonomous Prefecture Guizhou 550400 CN
- 代理机构: Epping - Hermann - Fischer
- 优先权: CN201510595122 20150918
- 国际公布: WO2017045519 20170323
- 主分类号: C01B25/231
- IPC分类号: C01B25/231 ; C01F11/46
摘要:
Provided is a method for producing wet-process phosphoric acid and by-producing alpha-hemihydrate gypsum and high-purity and high-whiteness alpha-hemihydrate gypsum. The method comprises: adding phosphoric acid and a phosphate rock powder into an extraction tank and conducting an extraction reaction on same, then adding sulfuric acid to continue the reaction so as to make 30%-50% of calcium ions form dihydrate gypsum, the dihydrate gypsum part being sent to a crystal transformation tank, a crystal transformation agent being added, and crystal transformation conditions being controlled so as to obtain 30%-50% of an ordinary alpha-hemihydrate gypsum; and make the other 50%-70% of calcium ions be present in the form of calcium dihydrogen phosphate in a phosphoric acid extractive solution, separating same and then introducing the phosphoric acid extractive solution into a decalcification reaction tank, adding a sulfuric acid solution diluted by a washing solution, and then firstly performing decalcification, and then controlling the crystal transformation conditions and subjecting a solid to a crystal transformation reaction, so as to generate a high-purity and high-whiteness alpha-hemihydrate gypsum. The method not only reduces the content of phosphorus in the by-product alpha-hemihydrate gypsum, but also realizes the industrial production of phosphoric acid and by-products ordinary alpha-hemihydrate gypsum and high-purity and high-whiteness alpha-hemihydrate gypsum by a wet-process.
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