- 专利标题: CATALYST FOR PREPARING CHLORINE BY HYDROGEN CHLORIDE OXIDATION, AND PREPARATION METHOD AND APPLICATION THEREOF
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申请号: EP16911312.3申请日: 2016-08-05
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公开(公告)号: EP3450014A1公开(公告)日: 2019-03-06
- 发明人: ZHANG, Hongke , ZHOU, Bo , ZAI, Zhangwei , XU, Dan , YAO, Yu , XU, Yanlong , ZHAO, Dongke , YANG, Jingjing , DING, Jiansheng , HUA, Weiqi
- 申请人: Wanhua Chemical Group Co., Ltd.
- 申请人地址: No. 17, Tianshan Rd, YEDA Yantai, Shandong 264000 CN
- 专利权人: Wanhua Chemical Group Co., Ltd.
- 当前专利权人: Wanhua Chemical Group Co., Ltd.
- 当前专利权人地址: No. 17, Tianshan Rd, YEDA Yantai, Shandong 264000 CN
- 代理机构: Dehns
- 优先权: CN201610625612 20160803
- 国际公布: WO2018023717 20180208
- 主分类号: B01J23/83
- IPC分类号: B01J23/83 ; B01J37/02 ; C01B7/04
摘要:
A catalyst for preparing chlorine gas by hydrogen chloride oxidation, comprising the following components calculated according to mass content based on the total weight of the catalyst: 0.5-20 wt% copper; 2-10 wt% manganese; 0.05-2 wt% boron; 0.01-3 wt% chromium; 0.1-10 wt% rare earth metal; 0.1-10 wt% potassium; and 3-15 wt% titanium; also comprising 0.02-1.1 wt% phosphorus; and 0.03-1.9 wt% iron; the carrier content is 55-90 wt%. In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80 - 85%. Almost all of the 0-1000 mg/kg of chlorinated benzene contained in hydrogen chloride gas can be converted into CO 2 and H 2 O without generating polychlorinated benzene.
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