公开(公告)号：EP3450014A1

公开(公告)日：2019-03-06

申请号：EP16911312.3

申请日：2016-08-05

申请人： Wanhua Chemical Group Co., Ltd.

发明人： ZHANG, Hongke ,  ZHOU, Bo ,  ZAI, Zhangwei ,  XU, Dan ,  YAO, Yu ,  XU, Yanlong ,  ZHAO, Dongke ,  YANG, Jingjing ,  DING, Jiansheng ,  HUA, Weiqi

IPC分类号： B01J23/83 ,  B01J37/02 ,  C01B7/04

摘要： A catalyst for preparing chlorine gas by hydrogen chloride oxidation, comprising the following components calculated according to mass content based on the total weight of the catalyst: 0.5-20 wt% copper; 2-10 wt% manganese; 0.05-2 wt% boron; 0.01-3 wt% chromium; 0.1-10 wt% rare earth metal; 0.1-10 wt% potassium; and 3-15 wt% titanium; also comprising 0.02-1.1 wt% phosphorus; and 0.03-1.9 wt% iron; the carrier content is 55-90 wt%. In the case of a fluidized bed reactor, the present catalyst can achieve a one-way hydrogen chloride conversion rate of 80 - 85%. Almost all of the 0-1000 mg/kg of chlorinated benzene contained in hydrogen chloride gas can be converted into CO 2 and H 2 O without generating polychlorinated benzene.