- 专利标题: NEGATIVE ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY, AND METHOD OF MANUFACTURING NEGATIVE ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY
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申请号: EP18892217.3申请日: 2018-12-19
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公开(公告)号: EP3731315A1公开(公告)日: 2020-10-28
- 发明人: YAMAZAKI Toshiki , MASUDA Yoshiho
- 申请人: Tokai Carbon Co., Ltd.
- 申请人地址: 2-3 Kita-Aoyama 1-chome Minato-ku Tokyo 107-8636 JP
- 专利权人: Tokai Carbon Co., Ltd.
- 当前专利权人: Tokai Carbon Co., Ltd.
- 当前专利权人地址: 2-3 Kita-Aoyama 1-chome Minato-ku Tokyo 107-8636 JP
- 代理机构: Müller-Boré & Partner Patentanwälte PartG mbB
- 优先权: JP2017246208 20171222
- 国际公布: WO2019124425 20190627
- 主分类号: H01M4/587
- IPC分类号: H01M4/587 ; H01M4/36
摘要:
Provided is a negative electrode material for a lithium-ion secondary battery having a sufficient strength capable of exerting a certain resistance to the applied pressure to maintain the electrolytic solution flow path and maintain the non-parallel orientation of the flat graphite constituting the graphite particle spherical aggregates when pressed during electrode formation while being deformed such that the graphite particle spherical aggregates reach a certain density or more, and thus capable of increasing the electrode density and improving discharge capacity and excellent in cycle characteristics.
A negative electrode material for a lithium-ion secondary battery contains a mass of graphite particle spherical aggregates in which a plurality of flat graphite particles are aggregated. The mass of the graphite particle spherical aggregates has an average circularity, D 90 /D 10 , and a crystallite size Lc (004) within a predetermined range, and the proportion of the graphite particle spherical aggregates in which the largest flat graphite particle observed on the outermost surface has a circle equivalent diameter of 2 µm to 12 µm in graphite particle spherical aggregates having a circle equivalent diameter of 10 µm or more when observed by SEM is 80% or more.
A negative electrode material for a lithium-ion secondary battery contains a mass of graphite particle spherical aggregates in which a plurality of flat graphite particles are aggregated. The mass of the graphite particle spherical aggregates has an average circularity, D 90 /D 10 , and a crystallite size Lc (004) within a predetermined range, and the proportion of the graphite particle spherical aggregates in which the largest flat graphite particle observed on the outermost surface has a circle equivalent diameter of 2 µm to 12 µm in graphite particle spherical aggregates having a circle equivalent diameter of 10 µm or more when observed by SEM is 80% or more.
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