发明公开
- 专利标题: CONTINUOUS LOW-TEMPERATURE PROCESS TO PRODUCE TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE
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申请号: EP22173899.0申请日: 2011-08-30
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公开(公告)号: EP4067325A3公开(公告)日: 2023-01-25
- 发明人: Pokrovski, Konstantin A. , Merkel, Daniel C. , Tung, Hsueh Sung
- 申请人: Honeywell International Inc.
- 申请人地址: US Morris Plains, NJ 07950 115 Tabor Road
- 代理机构: Stepney, Gregory John
- 优先权: US201113220212 20110829
- 主分类号: C07C17/20
- IPC分类号: C07C17/20 ; C07C17/38 ; C07C21/18 ; C01B7/01 ; B01J19/18 ; C07C17/25
摘要:
Disclosed is process for the production of (E) 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)) by conducting a continuous reaction without the use of a catalyst. Also disclosed is an integrated system for producing hydrofluoro olefins, particularly 1233zd(E). The manufacturing process includes six major unit operations: (1) a fluorination reaction of HCC-240fa (in continuous or semi-batch mode) using HF with simultaneous removal of by-product HCl and the product 1233zd(E); (2) recycle of unreacted HCC-240fa and HF together with under-fluorinated by-products back to (1); (3) separation and purification of by-product HCl; (4) separation of excess HF back to (1); (5) purification of final product, 1233zd(E); and (6) isomerization of by-product 1233zd(Z) to 1233zd(E) to maximize the process yield.
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