A method of non-terrestrial network (NTN) communication and a user equipment (UE) using the same method are provided. The method includes: receiving a cell change command comprising re-synchronization information (S1501); and performing a re-synchronization procedure according to the re-synchronization information, wherein the re-synchronization information comprising at least one of the following:a re-synchronization time; ephemeris information associated with a target cell; timing advance adjustment information associated with the target cell; a timing advance command value associated with the target cell; and a re-synchronization indication for indicating the UE to perform the re-synchronization procedure, wherein the re-synchronization procedure comprises a downlink re-synchronization procedure (S1502).