- Patent Title: Nickel manganese composite hydroxide particles and manufacturing method thereof, cathode active material for a non-aqueous electrolyte secondary battery and manufacturing method thereof, and a non-aqueous electrolyte secondary battery
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Application No.: US13820110Application Date: 2011-03-28
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Publication No.: US10017875B2Publication Date: 2018-07-10
- Inventor: Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
- Applicant: Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
- Applicant Address: JP Tokyo
- Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Finnegan, Henderson, Farabow, Garrett & Dunner LLP
- International Application: PCT/JP2011/057694 WO 20110328
- International Announcement: WO2012/131881 WO 20121004
- Main IPC: H01M10/0525
- IPC: H01M10/0525 ; C30B7/14 ; H01M4/505 ; H01M4/525 ; C01G53/00 ; H01M4/04 ; H01M4/36

Abstract:
Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.
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