A vehicle mutual-charging system and a charging connector are provided. The system includes: a first electric vehicle (1002) and a second electric vehicle (1003), each of the first electric vehicle (1002) and the second electric vehicle (1003) including a power battery (10), a battery manager (103), an energy control device (1005) and a charge-discharge socket (20), in which the energy control device (1005) includes: a three-level bidirectional DC-AC module (30), a charge-discharge control module (50), a control module (60); and a charging connector (1004) connected between the first electric vehicle (1002) and the second electric vehicle (1003) and including a first charging gun adaptor connected with the charge-discharge socket (20) of the first electric vehicle and a second charging gun adaptor connected with the charge-discharge socket (20) of the second electric vehicle at both ends thereof respectively.