Methods of forming multi-component reinforced composites are described. The methods may include forming a particle-reinforced component and a polymer-containing component where the particle-reinforced component and the polymer-containing component are in contact with one another. The particle reinforced component may be formed by a process that includes providing reactive particles that have a reactive polymerization promoter chemically bonded or coated on the surface of the reactive particles and contacting the reactive particles with a resin solution that includes monomers of a polymer. The polymerization promoter chemically bonded or coated on the surface of the reactive particles may promote the polymerization of the monomers. The resin solution may subsequently be polymerized forming a polymer matrix around the reactive particles.