Invention Grant
- Patent Title: Method for producing diesters of terephthalic acid with a dehydration of recirculated alcohol
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Application No.: US15513757Application Date: 2015-09-21
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Publication No.: US10207978B2Publication Date: 2019-02-19
- Inventor: Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
- Applicant: BASF SE
- Applicant Address: DE
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE
- Agency: Drinker Biddle & Reath LLP
- Priority: EP14186143 20140924
- International Application: PCT/EP2015/071576 WO 20150921
- International Announcement: WO2016/046118 WO 20160331
- Main IPC: C07C67/08
- IPC: C07C67/08 ; B01J19/18 ; C07C69/82

Abstract:
The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase, the organic phase is dewatered and the dewatered organic phase is passed at least partly into the dispersing tank.
Public/Granted literature
- US20170297997A1 METHOD FOR PRODUCING DIESTERS OF TEREPHTHALIC ACID WITH A DEHYDRATION OF RECIRCULATED ALCOHOL Public/Granted day:2017-10-19
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