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1.发明授权公开(公告)号：US10239818B2
公开(公告)日：2019-03-26
申请号：US15513716
申请日：2015-09-21
Applicant: BASF SE
Inventor： Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, a reaction suspension is drawn off from a region between the upper region and the lower region of the reactor, a first stream of the reaction suspension is recycled into the upper region of the reactor and a second stream of the reaction suspension is introduced into the lower region of the reactor, and the reaction suspension is thus mixed, wherein the stream drawn off and/or the first stream is passed through a heat exchanger outside the reactor and heated; and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is at least partly recycled into the reaction system.
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2.发明授权公开(公告)号：US10266477B2
公开(公告)日：2019-04-23
申请号：US15513775
申请日：2015-09-21
Applicant: BASF SE
Inventor： Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is conducted through a column in which the organic phase is run counter to at least a portion of the vapor, and the organic phase is collected in the lower region of the column and at least partly passed into the dispersing tank.
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公开(公告)号：US09988338B2
公开(公告)日：2018-06-05
申请号：US15513730
申请日：2015-09-21
Applicant: BASF SE
Inventor： Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
IPC: C07C67/08
Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst to obtain a reaction suspension, a stream of the reaction suspension is drawn off from the reactor, passed through a heat exchanger outside the reactor and heated and the heated reaction suspension is recycled into the reactor, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is at least partly recycled into the reactor.
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4.发明授权公开(公告)号：US10207978B2
公开(公告)日：2019-02-19
申请号：US15513757
申请日：2015-09-21
Applicant: BASF SE
Inventor： Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
Abstract: The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase, the organic phase is dewatered and the dewatered organic phase is passed at least partly into the dispersing tank.
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