- 专利标题: Method for the preparation of polyaniline/reduced graphene oxide composites
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申请号: US15521328申请日: 2015-10-29
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公开(公告)号: US10253155B2公开(公告)日: 2019-04-09
- 发明人: Sergio Bocchini , Alessandro Chiolerio , Samuele Porro
- 申请人: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- 申请人地址: IT Genoa
- 专利权人: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- 当前专利权人: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- 当前专利权人地址: IT Genoa
- 代理机构: Marshall, Gerstein & Borun LLP
- 优先权: ITTO2014A0882 20141029
- 国际申请: PCT/IB2015/058356 WO 20151029
- 国际公布: WO2016/067243 WO 20160506
- 主分类号: H01B1/08
- IPC分类号: H01B1/08 ; C08K3/04 ; C09D11/322 ; C09D11/52 ; C08G73/02 ; H01G11/32 ; H01G11/86 ; H01B1/12 ; C01B32/182
摘要:
The present invention concerns a method for obtaining polyaniline/reduced graphene oxide composites comprising the steps of dispersing the graphene oxide in an acid aqueous solution containing an emulsifying agent to obtain a graphene oxide dispersion; dissolving one or more aniline oligomers in an organic solvent to obtain an oligomer solution; mixing the oligomer solution with the graphene oxide dispersion, said oligomer being added in a stoichiometric excess compared to the quantity required to complete the graphene oxide reduction; adding to the suspension of the polyaniline/reduced graphene oxide composite an oxidizing agent in a stoichiometric quantity compared to said excess of oligomer so as to oxidize the excess of said oligomer to obtain a suspension of the polyaniline/reduced graphene oxide composite.
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