A method for separating and quantifying gamma ray induced and neutron induced responses in a radiation detector includes detecting radiation in a radiation field comprising neutrons and gamma rays. The detected events are converted into a detector pulse amplitude spectrum. The pulse amplitude spectrum is decomposed into contributions from detected gamma rays and detected neutrons using gamma ray standard spectra and neutron standard spectra and a spectral fitting procedure which results in a best fit between a weighted sum of the contributions and the detector pulse amplitude spectrum. The fitting procedure includes determining fitting parameters for each of the standard spectra wherein at least one of the fitting parameters is different for the gamma ray standard spectra and the neutron standard spectra. In one embodiment, the fitting parameter is spectral gain.