Invention Grant
- Patent Title: Process for the preparation of glycols
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Application No.: US16060221Application Date: 2016-12-07
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Publication No.: US10294181B2Publication Date: 2019-05-21
- Inventor: Leslie Andrew Chewter , Jean Paul Andre Marie Joseph Ghislain Lange , Duraisamy Muthusamy , Timothy Michael Nisbet , Evert Van Der Heide , Pieter Huizenga
- Applicant: SHELL OIL COMPANY
- Applicant Address: US TX Houston
- Assignee: SHELL OIL COMPANY
- Current Assignee: SHELL OIL COMPANY
- Current Assignee Address: US TX Houston
- Priority: EP15198769 20151209
- International Application: PCT/EP2016/080116 WO 20161207
- International Announcement: WO2017/097847 WO 20170615
- Main IPC: C07C29/60
- IPC: C07C29/60 ; C07C31/00 ; B01J19/00 ; C07C29/132 ; B01J8/20 ; B01J8/22 ; B01J10/00 ; B01J16/00 ; B01J19/18 ; B01J19/24 ; C07C31/20

Abstract:
The invention provides a continuous process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, said process being carried out in a reactor system comprising a reactor vessel equipped with an external recycle loop and said process comprising the steps of: i) providing the starting material in a solvent, via an inlet, to the external recycle loop and contacting it therein with a retro-aldol catalyst composition to provide an intermediate stream; ii) then contacting said intermediate stream with hydrogen in the presence of a hydrogenation catalyst composition in the reactor vessel; iii) withdrawing a product stream comprising glycols from the reactor vessel; iv) providing a portion of said product stream, via an outlet, for separation and purification of the glycols contained therein; and v) recycling the remainder of said product stream via the external recycle loop.
Public/Granted literature
- US20180362424A1 PROCESS FOR THE PREPARATION OF GLYCOLS Public/Granted day:2018-12-20
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