The present disclosure provides solid multilayer structure having m polarization layers, and m+1 insulating layers disposed in a repeating sequence with the polarization layers, At least one polarization layer is comprised of materials selected from non-linear polarizable composite compounds and side chain polymers with non-linear polarizable pendants, and m is a number greater than or equal to 1. The insulating layer has a breakdown voltage greater than or equal to 0.01 volts (V) per nanometer (nm), and the polarization layer has a dielectric permittivity greater than or equal to 100. The solid multilayer structure may be used as a dielectric layer between two electrodes in capacitor.