A method for detecting the presence of foreign fluids on surface comprises estimating an expected polarization response for a foreign fluid desired to be detected. Oil from an oil spill is one such foreign fluid. A polarimeter records raw image data of a surface (e.g., the surface of water) to obtain polarized images of the surface. IR and polarization data products are computed from the polarized images. The IR and polarization data products are converted to multi-dimensional data set to form multi-dimensional imagery. Contrast algorithms are applied to the multi-dimensional imagery to form enhanced contrast images, from which foreign fluids can be automatically detected.