A liquid crystal display device includes: a first curved substrate; a second curved substrate facing the first curved substrate; a liquid crystal layer interposed between the first curved substrate and the second curved substrate; a first curved liquid crystal alignment layer interposed between the liquid crystal layer and the first curved substrate; and a second curved liquid crystal alignment layer interposed between the liquid crystal layer and the second curved substrate, wherein the second curved liquid crystal alignment layer includes a nanoparticles including a hydrophobic group and a hydrophilic group.