A carbon dioxide capture and release method of forming a MOF matrix material including at least one metal-organic-framework crystal that includes at least one metal ion or metal ion cluster coordinated to polydentate organic ligands. The method includes forming a positive moisture swing CO2 host by application of at least a portion of the MOF matrix material to at least a portion of a good, and exposing the good to a feed gas. The method also includes altering the absorption and desorption of CO2 in the CO2 host through a swing absorption/desorption process of moisture content, where an equilibrium pressure of CO2 over the CO2 host is based at least in part on the moisture content. The metal-organic-framework crystal can be UIO-66 including Zr6O4(OH)4(CO2)12 clusters linked by terephthalate acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by amino-terephthalic acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by nitro-terephthalic acid ligands.