公开(公告)号：US10413858B2

公开(公告)日：2019-09-17

申请号：US15392466

申请日：2016-12-28

Applicant: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

Inventor： Bin Mu ,  Mitchell Armstrong ,  Allen Wright ,  Klaus Lackner

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/22 ,  B01J20/08 ,  B01J20/28 ,  B01J20/34

Abstract: A carbon dioxide capture and release method of forming a MOF matrix material including at least one metal-organic-framework crystal that includes at least one metal ion or metal ion cluster coordinated to polydentate organic ligands. The method includes forming a positive moisture swing CO2 host by application of at least a portion of the MOF matrix material to at least a portion of a good, and exposing the good to a feed gas. The method also includes altering the absorption and desorption of CO2 in the CO2 host through a swing absorption/desorption process of moisture content, where an equilibrium pressure of CO2 over the CO2 host is based at least in part on the moisture content. The metal-organic-framework crystal can be UIO-66 including Zr6O4(OH)4(CO2)12 clusters linked by terephthalate acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by amino-terephthalic acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by nitro-terephthalic acid ligands.

公开(公告)号：US20170182453A1

公开(公告)日：2017-06-29

申请号：US15392466

申请日：2016-12-28

Applicant: ARIZONA BOARD OF REGENTS ON BEHALF OF ARIZONA STATE UNIVERSITY

Inventor： BIN MU ,  Mitchell Armstrong ,  Allen Wright ,  Klaus Lackner

IPC: B01D53/04 ,  B01J20/34 ,  B01J20/28 ,  B01J20/22 ,  B01J20/08

CPC classification number: B01D53/0454 ,  B01D53/02 ,  B01D53/04 ,  B01D2253/204 ,  B01D2253/306 ,  B01D2257/504 ,  B01D2259/40083 ,  B01D2259/40086 ,  B01J20/08 ,  B01J20/226 ,  B01J20/28016 ,  B01J20/3425 ,  B01J20/3458 ,  Y02C10/08

Abstract: A carbon dioxide capture and release method of forming a MOF matrix material including at least one metal-organic-framework crystal that includes at least one metal ion or metal ion cluster coordinated to polydentate organic ligands. The method includes forming a positive moisture swing CO2 host by application of at least a portion of the MOF matrix material to at least a portion of a good, and exposing the good to a feed gas. The method also includes altering the absorption and desorption of CO2 in the CO2 host through a swing absorption/desorption process of moisture content, where an equilibrium pressure of CO2 over the CO2 host is based at least in part on the moisture content. The metal-organic-framework crystal can be UIO-66 including Zr6O4(OH)4(CO2)12 clusters linked by terephthalate acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by amino-terephthalic acid ligands, and/or Zr6O4(OH)4(CO2)12 clusters linked by nitro-terephthalic acid ligands.