Invention Grant
- Patent Title: Process for the preparation of a purified acid composition
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Application No.: US15579256Application Date: 2016-06-06
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Publication No.: US10464913B2Publication Date: 2019-11-05
- Inventor: Ana Rita Martins Guerreiro Rocha Almeida , Martinus Mathilda Pieter Zieverink , Ana Sofia Vagueiro De Sousa Dias , Ines Dacil Gonzalez Jimenez
- Applicant: Synvina C.V.
- Applicant Address: NL Amsterdam
- Assignee: Synvina C.V.
- Current Assignee: Synvina C.V.
- Current Assignee Address: NL Amsterdam
- Agency: Hoffmann & Baron, LLP
- Priority: NL2014923 20150605
- International Application: PCT/NL2016/050405 WO 20160606
- International Announcement: WO2016/195500 WO 20161208
- Main IPC: C07D307/68
- IPC: C07D307/68 ; B01J23/34 ; B01J23/75 ; B01J27/08 ; C07B31/00 ; C07B33/00 ; C07B41/02 ; C07B63/02

Abstract:
A purified acid composition including 2,5-furandicarboxylic acid is prepared in a process, including oxidizing a feedstock containing 5-alkoxymethylfurfural to an oxidation product including 2,5-furandicarboxylic acid (FDCA) and 2-formyl-furan-5-carboxylic acid (FFCA), and esters of FDCA and, optionally, esters of FFCA; hydrolyzing the at least part of the oxidation product in the presence of water, thereby hydrolyzing at least esters of FDCA and, optionally, esters of FFCA to obtain an aqueous solution of an acid composition including FDCA, FFCA and ester of FDCA in an amount below the amount of ester of FDCA in the solution of the oxidation product; contacting at least part of the solution of the acid composition with hydrogen in the presence of a hydrogenation catalyst to hydrogenate FFCA to hydrogenation products, yielding a hydrogenated solution; and separating at least a portion of the FDCA from at least part of the hydrogenated solution by crystallization.
Public/Granted literature
- US20180155308A1 PROCESS FOR THE PREPARATION OF A PURIFIED ACID COMPOSITION Public/Granted day:2018-06-07
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