The invention relates to a process for preparing an electrically conductive composite film, in particular in the form of a self-supported film or of a prepreg, comprising at least one thermoplastic polymer resin and electrically conductive particles chosen from a) graphene, carbon nanotubes, carbon nanofibres, and mixtures thereof; and b) filiform metal nanoparticles; to a process for preparing an electrically conductive laminated composite structure comprising such an electrically conductive composite film; to said electrically conductive composite film, to said electrically conductive laminated composite structure, and also to the uses thereof.