The invention relates to multilayer composites having improved weathering properties without reducing flame retardation properties. The composites have a fluoropolymer layer over a thermoplastic layer. The multilayer composite may be a fluoropolymer layer directly over a relatively flammable substrate or non-flammable substrate (like PVC), or it may be a fluoropolymer layer over a relatively flammable cap layer, over a substrate (that is flammable or non-flammable). The composite is formed using coating, coextrusion and/or lamination techniques. The multilayer composite is especially useful in articles having surfaces that are used in a relatively horizontal position, including decking, railings, roofing and window profiles. The composites provide improved weathering for the substrate without a reduction in flame-resistance, when compared to the substrate without the outer fluoropolymer layer. The multi-layer composite also provides enhanced chemical resistance, hardness, scratch and mar, and water resistance.