Invention Grant
- Patent Title: Process for the preparation of a semi-crystalline semi-aromatic polyamide
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Application No.: US15321406Application Date: 2014-06-26
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Publication No.: US10577500B2Publication Date: 2020-03-03
- Inventor: Johannes Hoekstra , Rudy Rulkens , Hans Klaas Dijk,Van
- Applicant: DSM IP Assets B.V.
- Applicant Address: NL Heerlen
- Assignee: DSM IP ASSETS B.V.
- Current Assignee: DSM IP ASSETS B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- International Application: PCT/EP2014/063584 WO 20140626
- International Announcement: WO2015/197124 WO 20151230
- Main IPC: C08L77/06
- IPC: C08L77/06 ; C08G69/26 ; C08G69/28 ; C08G69/30 ; C08K7/14 ; C08K3/40 ; C08L77/00 ; C08G81/00 ; B29B7/00 ; B29B7/82 ; B29C45/00 ; B29C45/72 ; B29K77/00

Abstract:
The invention relates to a process for the preparation of a semi-crystalline semi-aromatic polyamide copolymer (Co-PA) having a melting temperature (Tm-Co-PA) of at least 300° C., comprising steps of (a) preparing a first semi-crystalline semi-aromatic polyamide (A), having a melting temperature (Tm-A) of at least 310° C.; and consisting of repeat units derived from 45-50 mol % terephthalic acid; 47.5-50 mol % of diamine; and 0-5 mol % of one or more other amine and/or acid group containing components; the mol % being relative to the total molar amount of said amine and/or acid group containing components; and wherein poly-amide (A) is prepared by a process comprising direct solid-state polymerization of a diamine-dicarboxylic acid salt of the terephthalic acid and the diamine; (b) providing a polyamide (B), being an amorphous polyamide having a glass transition temperature (Tg-B) below Tm-A, or a second semi-crystalline polyamide having a melting temperature (Tm-B) below Tm-A, or a combination of the amorphous polyamide and the second semi-crystalline polyamide; (c) heating and melt-mixing polyamide (A) and polyamide (B), thereby obtaining a miscible polymer melt with a temperature (T-melt) above Tm-A; and (d) cooling the melt to a temperature below the solidification temperature of the melt, thereby obtaining a solid semi-crystalline semi-aromatic polyamide copolymer.
Public/Granted literature
- US20170152382A1 PROCESS FOR THE PREPARATION OF A SEMI-CRYSTALLINE SEMI-AROMATIC POLYAMIDE Public/Granted day:2017-06-01
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