Invention Grant
- Patent Title: Reverse-phase polymerisation process
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Application No.: US14908823Application Date: 2014-07-29
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Publication No.: US10604611B2Publication Date: 2020-03-31
- Inventor: John Scott Barratt , Aleksandra Jelicic , Pascal Hesse , Oliver Soetje , Robert Haschick , Gabriela Eugenia Fonseca Zepeda , Shankara Narayanan Keelapandal Ramamoorthy , Sandra Jeck , Jelan Kuhn
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP13178691 20130731
- International Application: PCT/EP2014/066251 WO 20140729
- International Announcement: WO2015/014824 WO 20150205
- Main IPC: C08F265/04
- IPC: C08F265/04 ; C08J11/02 ; C08F2/32 ; B01J19/12 ; B01D61/14 ; B01J19/24 ; B01J4/00 ; B01D61/02 ; C08J3/12 ; C08F220/56 ; C08F220/20 ; C08F220/06 ; C08F220/38 ; C08F226/10

Abstract:
A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then transferring the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises removing particles from the non-aqueous liquid in at least one filtration step. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. The invention further relates to a cleaned non-aqueous liquid obtainable by the process.
Public/Granted literature
- US20160159958A1 REVERSE-PHASE POLYMERISATION PROCESS Public/Granted day:2016-06-09
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